Evaluation of the temporal behavior of fulvic acid iron in Asahi River, Okayama, Japan
Rohdof Lactem Yengeh, Hiroaki Somura, Toshitsugu Moroizumi, Yasushi Mori, Morihiro Maeda
Received 30 May, 2024
Accepted 2 September, 2024
Published online 6 March, 2025
Rohdof Lactem Yengeh1), Hiroaki Somura1), Toshitsugu Moroizumi1), Yasushi Mori1), Morihiro Maeda1)
1) Graduate School of Environmental and Life Science, Okayama University, Japan
Iron is essential for biogeochemical processes in aquatic ecosystems, but its riverine concentration can be affected by environmental conditions. This study assessed weekly fulvic acid iron (FAFe) concentration at a single sampling site in Asahi River from 2022–2023 to explore the differences in the temporal scales. The objectives of this study were to evaluate the effects of physicochemical properties of the river on the concentration of FAFe, analyze the concentration of FAFe in spring, summer, autumn and winter, and assess the relationship between FAFe concentration and land use types of the watershed. The results indicated that physicochemical parameters, such as pH and surface water temperature (SWT) seemed to influence FAFe concentration (p < 0.05). Hydrological dynamics influenced FAFe concentration and transport, revealing an increasing trend during spring (p < 0.001) and summer (p = 0.05), with non-significant trends during autumn and winter (p > 0.05). FAFe exhibited a strong positive correlation with total organic carbon (TOC) (p < 0.001). Upland fields significantly influenced FAFe concentration (p < 0.01) through runoff with abundant NO3– and PO43– into the river. Thus, FAFe concentration in Asahi River was influenced by pH, SWT, TOC, hydrological regime, and agricultural runoff.
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